By Gary L. Miessler, Donald A. Tarr, Paul J. Fischer
With its updates to fast altering content material parts, a bolstered visible presentation and the addition of recent co-author Paul Fischer, the recent variation of this hugely readable textual content is extra academic and helpful than ever. Inorganic Chemistry, 5/e delivers the necessities of Inorganic Chemistry at simply the proper point for today’s school room — neither too excessive (for beginner readers) nor too low (for complicated readers). powerful insurance of atomic thought and an emphasis on actual chemistry offer an organization realizing of the theoretical foundation of inorganic chemistry, whereas a reorganized presentation of molecular orbital and team thought highlights key rules extra clearly.
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Extra resources for Inorganic Chemistry (5th Edition)
Pearsonhighered. com ISBN-10: 0-321-81105-4 ISBN-13: 978-0-321-81105-9 Brief Contents bankruptcy 1 advent to Inorganic Chemistry 1 bankruptcy 2 Atomic constitution nine bankruptcy three easy Bonding concept forty five bankruptcy four Symmetry and crew idea seventy five bankruptcy five Molecular Orbitals 117 bankruptcy 6 Acid–Base and Donor–Acceptor Chemistry 169 bankruptcy 7 The Crystalline reliable kingdom 215 bankruptcy eight Chemistry of the most staff components 249 bankruptcy nine Coordination Chemistry I: constructions and Isomers 313 bankruptcy 10 Coordination Chemistry II: Bonding 357 bankruptcy eleven Coordination Chemistry III: digital Spectra 403 bankruptcy 12 Coordination Chemistry IV: Reactions and Mechanisms 437 bankruptcy thirteen Organometallic Chemistry 475 bankruptcy 14 Organometallic Reactions and Catalysis 541 bankruptcy 15 Parallels among major staff and Organometallic Chemistry 579 Appendix A solutions to workouts 619 Appendix B beneficial info App. B are available on-line at www. pearsonhighered. com/advchemistry Appendix C personality Tables 658 iii Contents Preface xi Acknowledgments xiii bankruptcy 1 advent to Inorganic Chemistry 1 1. 1 what's Inorganic Chemistry? 1 1. 2 Contrasts with natural Chemistry 1 1. three The background of Inorganic Chemistry four 1. four viewpoint 7 normal References eight bankruptcy 2 Atomic constitution nine 2. 1 ancient improvement of Atomic conception nine 2. 1. 1 The Periodic desk 10 2. 1. 2 Discovery of Subatomic debris and the Bohr Atom eleven 2. 2 The Schrödinger Equation 14 2. 2. 1 The Particle in a field sixteen 2. 2. 2 Quantum Numbers and Atomic Wave features 18 2. 2. three The Aufbau precept 26 2. 2. four protecting 30 2. three Periodic houses of Atoms 36 2. three. 1 Ionization strength 36 2. three. 2 Electron Affinity 37 2. three. three Covalent and Ionic Radii 38 common References forty-one bankruptcy three • difficulties forty-one basic Bonding idea forty five three. 1 Lewis Electron-Dot Diagrams forty five three. 1. 1 Resonance forty six three. 1. 2 larger Electron Counts forty six three. 1. three Formal cost forty seven three. 1. four a number of Bonds in Be and B Compounds forty nine three. 2 Valence Shell Electron-Pair Repulsion fifty one three. 2. 1 Lone-Pair Repulsion fifty three three. 2. 2 a number of Bonds fifty five three. 2. three Electronegativity and Atomic dimension results fifty seven three. 2. four Ligand shut Packing sixty three three. three Molecular Polarity sixty six three. four Hydrogen Bonding sixty seven common References 70 bankruptcy four • difficulties seventy one Symmetry and crew concept seventy five four. 1 Symmetry components and Operations seventy five four. 2 aspect teams eighty four. 2. 1 teams of high and low Symmetry eighty two four. 2. 2 different teams eighty four four. three homes and Representations of teams ninety four. three. 1 Matrices ninety one four. three. 2 Representations of aspect teams ninety two four. three. three personality Tables ninety five iv Contents | v four. four Examples and purposes of Symmetry a hundred four. four. 1 Chirality a hundred four. four. 2 Molecular Vibrations one hundred and one normal References bankruptcy five 111 • difficulties 111 Molecular Orbitals 117 five. 1 Formation of Molecular Orbitals from Atomic Orbitals 117 five. 1. 1 Molecular Orbitals from s Orbitals 118 five. 1. 2 Molecular Orbitals from p Orbitals one hundred twenty five. 1. three Molecular Orbitals from d Orbitals 121 five. 1. four Nonbonding Orbitals and different components 122 five.